Solid-state aggregation of metallacyclophane-based Mn(II)Cu(II) one-dimensional ladders |
| |
| Authors: | Ferrando-Soria Jesús Grancha Thais Pasán Jorge Ruiz-Pérez Catalina Cañadillas-Delgado Laura Journaux Yves Julve Miguel Cano Joan Lloret Francesc Pardo Emilio |
| |
| Institution: | Departament de Química Inorgànica, Instituto de Ciencia Molecular (ICMOL), Universitat de València, 46980 Paterna, València, Spain. |
| |
| Abstract: | Two distinct one-dimensional (1) and two-dimensional (2) mixed-metal-organic polymers have been synthesized by using the "complex-as-ligand" strategy. The structure of 1 consists of isolated ladderlike Mn(II)(2)Cu(II)(2) chains separated from each other by neutral Mn(II)(2) dimers, whereas 2 possesses an overall corrugated layer structure built from additional coordinative interactions between adjacent Mn(II)(2)Cu(II)(2) ladders. Interestingly, 1 and 2 show overall ferri- and antiferromagnetic behavior, respectively, as a result of their distinct crystalline aggregation in the solid state. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
