[RhCl(CO)(PPh3)]2. A precursor for the synthesis of cationic rhodium complexes with nitrogen donor ligands |
| |
| Authors: | Rafael Usón Luis A. Oro Daniel Carmona Maria Pilar Lamata |
| |
| Affiliation: | (1) Department of Inorganic Chemistry, University of Zaragoza, Zaragoza, Spain |
| |
| Abstract: | Summary The use of [RhCl(CO)(PPh3)]2 as a precursor for the synthesis of complexes of the types [Rh(CO)L2(PPh3)]A (A = [ClO4]– or [BPh4]–; L = pyridine type ligand) and [Rh(CO)(L-L)(PPh3)]A (A = [ClO4]– or [BPh4]–; L-L = bidentate nitrogen donor) and the preparation of several complexes of the types [Rh(CO)L(PPh3){P(p-RC6H4)3}]BPh4 and [Rh(CO)(phen)(PPh3){P(p-RC6H4)3}]A (A = [ClO4]– or [BPh4]–; R = H or Me) is described.Author to whom all correspondence should be directed. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
