Controlled diastereoselectivity at the alkene-geometry through selective encapsulation: E-Z photoisomerization of oxazolidinone-functionalized enecarbamates within hydrophobic nano-cavities |
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| Authors: | Saito Hideaki Sivaguru J Jockusch Steffen Dyer Joanne Inoue Yoshihisa Adam Waldemar Turro Nicholas J |
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| Affiliation: | Department of Chemistry, Columbia University, 3000 Broadway, Mail Code 3119, New York, NY 10027, USA. |
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| Abstract: | ![]()
Photoisomerization of encapsulated Z-enecarbamates within the hydrophobic chiral cavities of gamma-CD showed higher diastereoselectivities in the photoproducts than those obtained in solution. The selective encapsulation of the enecarbamates and the following isomerization process are both diastereoselectively controlled by gamma-CD. |
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