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ChemInform Abstract: Reactions of Lanthanide Atoms with Oxygen Difluoride and the Role of the Ln Oxidation State. |
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| Authors: | Tanya Mikulas Mingyang Chen David A. Dixon Kirk A. Peterson Yu Gong Lester Andrews |
| Affiliation: | Dep. Chem., Univ. Va., Charlottesville, VA 22904, USA |
| Abstract: | Oxidative addition products OLnF2 (Ln: lanthanide) and OLnF are obtained by condensation of laser-ablated Ln atoms with OF2 in excess argon or neon at 4 K. |
| Keywords: | IR and Raman spectra (atoms and molecules) reactions (including homogeneous catalysis) lanthanoids oxygen, O fluorine, F |