Electricoswitchable bonding of metal ions and complexes by calixarenes |
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| Authors: | V V Yanilkin A R Mustafina A S Stepanov N V Nastapova G R Nasybullina A Yu Ziganshina S E Solovieva A I Konovalov |
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| Institution: | 1.Arbuzov Institute of Physical and Organic Chemistry,Kazan Scientific Center, Russian Academy of Sciences,Kazan,Russia |
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| Abstract: | The results of authors on designing electroswitchable supramolecular systems based on calix4]arenes, calix4]resorcinols,
and transition metal ions and complexes are summarized. We consider systems in which the switching is performed owing to electrochemical
reactions both of groups grafted to the macrocycle and bound substrates. Examples of electrochemically switchable luminescence
are given. |
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