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THE EFFECT OF ETHERS ON ALTERNATING COPOLYMERIZATION OF BUTADIENE AND PROPYLENE CATALYZED BY VANADIUM-ALUMINUM SYSTEM
作者姓名:苏丹  余鼎声  胡力平  焦书科
作者单位:Department of Applied Chemistry,Beijing Institute of Chemical Technology,Beijing,Department of Applied Chemistry,Beijing Institute of Chemical Technology,Beijing,Department of Applied Chemistry,Beijing Institute of Chemical Technology,Beijing,Department of Applied Chemistry,Beijing Institute of Chemical Technology,Beijing
基金项目:The project was supported by the National Natural Science Foundation of China
摘    要:The effect of five ethers on alternating copolymerization of br(?)adiene and propylene were investigated. It was found that under appropriate conditions, by adding ether into reaction system, the conversion could be increased by 10-20% and the catalytic efficiency doubled at -45℃. The interaction between ether and active center was also studied.

收稿时间:1987-01-31

THE EFFECT OF ETHERS ON ALTERNATING COPOLYMERIZATION OF BUTADIENE AND PROPYLENE CATALYZED BY VANADIUM-ALUMINUM SYSTEM*
SU Dan,YU Dingsheng,HU Liping,JIAO Shuke.THE EFFECT OF ETHERS ON ALTERNATING COPOLYMERIZATION OF BUTADIENE AND PROPYLENE CATALYZED BY VANADIUM-ALUMINUM SYSTEM[J].Chinese Journal of Polymer Science,1988,0(1):56-63.
Authors:SU Dan  YU Dingsheng  HU Liping  JIAO Shuke
Institution:Department of Applied Chemistry; Beijing Institute of Chemical Technology; Beijing
Abstract: The effect of five ethers on alternating copolymerization of br+ adiene and propylene were investigated. It was found that under appropriate conditions, by adding ether into reaction system, the conversion could be increased by 10-20% and the catalytic efficiency doubled at -45℃. The interaction between ether and active center was also studied.
Keywords:Additives  butadiene-propylene alternating copolymer  vanadium-alummum catalyst  catalytic efficiency
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