Asymmetric epoxidation of styrenes catalyzed by molybdenum complexes with amino alcohol ligands |
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Authors: | Yi Wang |
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Affiliation: | Institute of Homogeneous Catalysis, College of Chemistry, Sichuan University, Chengdu 610064, China |
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Abstract: | Two common amino alcohols, prolinol and isolucinol, and their derivatives have been screened to coordinate with MoO2(acac)2 to form in situ catalysts for asymmetric epoxidation of styrenes with the highest enantioselectivity of 84% for 4-fluoro-styrene under the optimized reaction conditions. |
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Keywords: | Asymmetric epoxidation Styrene Molybdenum Amino alcohol |
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