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Synthesis and redox behavior of ene-diyne scaffolds that bear ferrocenes at the periphery
Authors:Taku Shoji  Shunji Ito  Noboru Morita
Affiliation:a Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan
b Graduate School of Science and Technology, Hirosaki University, Hirosaki 036-8561, Japan
Abstract:
The ene-diyne systems 1 and 2 possessing ferrocenyl groups at the periphery were prepared by the simple one-pot Sonogashira-Hagihara coupling reaction of ethynylferrocene with 9-dibromomethylene-9H-fluorene (4) and 9,10-bis(dibromomethylene)-9,10-dihydroanthracene (5). The novel ferrocene-substituted ene-diyne compounds exhibited amphoteric redox behavior with a reversible one-stage electrochemical oxidation upon cyclic voltammetry.
Keywords:
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