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Effect of the substituent on the phosphorus atom on the reaction of aminophosphines with 1-alkylisatins
Authors:L I Musin  A V Bogdanov  D B Krivolapov  A B Dobrynin  I A Litvinov  V F Mironov
Institution:1. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, ul. Arbuzova 8, Kazan, 420088, Tatarstan, Russia
Abstract:Depending on the substituent on the phosphorus(III) atom, reactions of tris(dialkylamino)phosphines, 2-diethylamino-1,3,2-benzodioxaphosphole, and benzene-1,4-diylbis(N,N,N′,N′-tetraethylphosphonous diamide) with 1-alkylisatins lead to the formation of isoindigo derivatives, spirophosphoranes, or spirooxiranes whose structure was determined by NMR spectroscopy and X-ray analysis.
Keywords:
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