Synthesis, properties, and structures of benzo[1,2-b:4,5-b']bis[b]benzothiophene and benzo[1,2-b:4,5-b']bis[b]benzoselenophene |
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Authors: | Ebata Hideaki Miyazaki Eigo Yamamoto Tatsuya Takimiya Kazuo |
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Affiliation: | Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University, Higashi-Hiroshima, 739-8527, Japan. |
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Abstract: | Employing two consecutive cyclization reactions, benzo[1,2-b:4,5-b']bis[b]benzochalcogenophenes, which are pi-extended heteroarenes, were efficiently synthesized. Their electronic and crystal structures were elucidated on the basis of UV-vis spectra, electrochemical measurements, and X-ray structural analyses. |
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