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Synthesis, properties, and structures of benzo[1,2-b:4,5-b']bis[b]benzothiophene and benzo[1,2-b:4,5-b']bis[b]benzoselenophene
Authors:Ebata Hideaki  Miyazaki Eigo  Yamamoto Tatsuya  Takimiya Kazuo
Affiliation:Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University, Higashi-Hiroshima, 739-8527, Japan.
Abstract:
Employing two consecutive cyclization reactions, benzo[1,2-b:4,5-b']bis[b]benzochalcogenophenes, which are pi-extended heteroarenes, were efficiently synthesized. Their electronic and crystal structures were elucidated on the basis of UV-vis spectra, electrochemical measurements, and X-ray structural analyses.
Keywords:
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