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Cobalt(Ⅱ) chloride accelerated one-pot three-component synthesis of α-aminophosphonates at room temperature
作者姓名:Zahed Karimi-Jaberi  Hassan Zare  Mohammad Amiri  Naghmeh Sadeghi
作者单位:Department of Chemistry, Islamic Azad University, Firoozabad Branch, P.O.Box 74715-117, Firoozabad, Fars, Iran
摘    要:A simple,efficient,and general method has been developed for the one-pot,three-component synthesis ofα-aminophosphonates from condensation reaction of trimethyl phosphite,aryl aldehydes and aryl amines in the presence of CoCl2-6H2O under solvent-free conditions.Thusα-aminophosphonates were synthesized relatively quickly in good yields at room temperature.

关 键 词:α-Aminophosphonates  Cobalt(Ⅱ)  chloride  Trimethyl  phosphite  Room  temperature  Solvent-free

Cobalt(Ⅱ) chloride accelerated one-pot three-component synthesis of α-aminophosphonates at room temperature
Zahed Karimi-Jaberi,Hassan Zare,Mohammad Amiri,Naghmeh Sadeghi.Cobalt(Ⅱ) chloride accelerated one-pot three-component synthesis of α-aminophosphonates at room temperature[J].Chinese Chemical Letters,2011,22(5):559-562.
Authors:Zahed Karimi-Jaberi  Hassan Zare  Mohammad Amiri  Naghmeh Sadeghi
Institution:Department of Chemistry, Islamic Azad University, Firoozabad Branch, P.O.Box 74715-117, Firoozabad, Fars, Iran
Abstract:A simple,efficient,and general method has been developed for the one-pot,three-component synthesis ofα-aminophosphonates from condensation reaction of trimethyl phosphite,aryl aldehydes and aryl amines in the presence of CoCl2-6H2O under solvent-free conditions.Thusα-aminophosphonates were synthesized relatively quickly in good yields at room temperature.
Keywords:α-Aminophosphonates  Cobalt(Ⅱ) chloride  Trimethyl phosphite  Room temperature  Solvent-free
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