| Synthesis and Characterization of a 1-D Zigzag Catenarian Compound [Sn（edt）2（p-phenylenediamine）]n |
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| 引用本文： | 王龙胜,张建军,杜文新,傅瑞标,吴新涛.Synthesis and Characterization of a 1-D Zigzag Catenarian Compound [Sn（edt）2（p-phenylenediamine）]n[J].结构化学,2005,24(9):1029-1032. |
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| 作者姓名： | 王龙胜 张建军 杜文新 傅瑞标 吴新涛 |
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| 作者单位： | State Key Laboratory of Structural Chemistry，Fujian Institute of Research on the Structure of Matter，The Chinese Academy of Sciences，Fuzhou，Fujian 350002，China，State Key Laboratory of Structural Chemistry，Fujian Institute of Research on the Structure of Matter，The Chinese Academy of Sciences，Fuzhou，Fujian 350002，China，State Key Laboratory of Structural Chemistry，Fujian Institute of Research on the Structure of Matter，The Chinese Academy of Sciences，Fuzhou，Fujian 350002，China，State Key Laboratory of Structural Chemistry，Fujian Institute of Research on the Structure of Matter，The Chinese Academy of Sciences，Fuzhou，Fujian 350002，China，State Key Laboratory of Structural Chemistry，Fujian Institute of Research on the Structure of Matter，The Chinese Academy of Sciences，Fuzhou，Fujian 350002，China |
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| 基金项目： | This research was supported by the State Key Laboratory of Structural Chemistry, the National Natural Science Foundation of China (20273073, 20333070, 90206040) and Natural Science Foundation of Fujian Province (2004J041, 2003J042, 2004HZ01-1) |
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| 摘 要： | 1 INTRODUCTION In recent years, the researches on tin sulfide ma- terials have drawn increasing attention of chemists owning to their potential applications as photo-vol- taic materials, holographic recording system1, 2], so- lar control devices3] and semiconductor materials. In the last decades, many finite adducts of tin (IV) thio- lates with organic amine ligands have been synthe- sized by self-assembly, such as cis-Sn(SPh)4(2,2?-bi- py)4], cis-Sn(edt)2(ethyldimiane)5], trans-Sn(…
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| 关 键 词： | 锡 聚合体 聚乙烯 硫醇盐 苯二胺 合成工艺 结构表征 |
Synthesis and Characterization of a 1-D Zigzag Catenarian Compound [Sn(edt)2(p-phenylenediamine)]n |
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| WANG Long-Sheng,ZHANG Jian-Jun,DU Wen-Xin,FU Rui-Biao,WU Xin-Tao.Synthesis and Characterization of a 1-D Zigzag Catenarian Compound [Sn(edt)2(p-phenylenediamine)]n[J].Chinese Journal of Structural Chemistry,2005,24(9):1029-1032. |
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| Authors: | WANG Long-Sheng ZHANG Jian-Jun DU Wen-Xin FU Rui-Biao WU Xin-Tao |
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| Institution: | State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, China |
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| Abstract: | A 1-D zigzag chain Sn(edt)2(p-phenylenediamine)]n (edt = ethane-1,2-thiolate) was synthesized by self-assembly and determined by X-ray structure analysis. The title compound (C10H16N2S4Sn) crystallizes in monoclinic, space group C2/c with a = 16.659(2), b = 7.0977(10), c = 12.4421(17) (A), β = 96.577(2)°, V= 1461.5(4) (A)3, Z = 4, Mr = 411.18, Dc = 1.869 g/cm3, F(000) = 816,μ = 2.300 mm-1, the final R = 0.0332 and wR = 0.0837 for 1142 observed reflections (I ＞ 2σ(Ⅰ)).In the complex, Sn4+ ion is six-coordinated with four sulfur atoms of two edt ligands from equatorial positions and two nitrogen atoms of p-phenylenediamine ligands from axial positions. The zigzag chain thus formed is parallel to the a axis. |
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| Keywords: | tin p-phenylenediamine ethene-1 2-thiolate polymer |
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