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Interplay of phenyl-perfluorophenyl stacking,C-H...F,C-F...pi and F...F interactions in some crystalline aromatic azines
Authors:Vangala Venu R  Nangia Ashwini  Lynch Vincent M
Institution:School of Chemistry, University of Hyderabad, Hyderabad 500 046, India.
Abstract:Analysis of phenyl-perfluorophenyl stacking synthon, C-H...F, C-F...pi interactions, and F...F tetramer in three closely related azine crystal structures shows the dominance of Ar-ArF synthon while other interactions are turned on/off depending on the H/F stoichiometry in the molecule.
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