First successful reaction of a silyl anion with hafnium tetrachloride |
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| Authors: | Frank Dieter Baumgartner Judith Marschner Christoph |
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| Affiliation: | Institut für Anorganische Chemie, Technische Universit?t Graz, Stremayrgasse 16, A-8010 Graz, Austria. |
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| Abstract: | ![]()
Hafnium tetrachloride reacts with the tris(trimethylsilyl)silyl potassium tmen adduct (1) to form a [tris(trimethylsilyl)silyl]trichlorohafnium tmen complex (2); reaction of 2 with 2,6-dimethylphenylisonitrile leads to insertion into the silicon hafnium bond (4). |
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