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Synthesis of multimetallic dendrimers through non-covalent interactions
Authors:Snelders Dennis J M  Virboul Morgane A N  Kreiter Robert  Versluis Cees  van Koten Gerard  Klein Gebbink Robertus J M
Affiliation:Organic Chemistry & Catalysis, Debye Institute for Nanomaterials Science, Faculty of Science, Utrecht University, Universiteitsweg 99, 3584 GC, Utrecht, The Netherlands.
Abstract:Hexa-ammonium functionalized Dendriphos ligands and mono-sulfonate functionalized metal complexes have been used as building blocks for the preparation of multimetallic dendritic assemblies. These metallodendrimers consist of a single metal centre surrounded by an oligocationic shell formed by the coordinated Dendriphos ligands and multiple associated anionic organometallic complexes.
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