| Crystal Structure of Calcium Complex with Cyanuric Acid Ligand［Ca（C_3H_3N_3O_3－O）（H_2O）_6］［（OH）（C_3H_2N_3O_3）］ |
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| 作者姓名： | Lin Zhou-Bin Chen Chang-Zhang Gao Dong-Shou Huang Xiao-Ying Li Ding |
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| 作者单位： | Fujian Institute of Research on the Structure of Matter，Chinese Academy of Sciences.Fuzhou，350002 |
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| 摘 要： | ＣｒｙｓｔａｌＳｔｒｕｃｔｕｒｅｏｆＣａｌｃｉｕｍＣｏｍｐｌｅｘｗｉｔｈＣｙａｎｕｒｉｃＡｃｉｄＬｉｇａｎｄ［Ｃａ（Ｃ_３Ｈ_３Ｎ_３Ｏ_３－Ｏ）（Ｈ_２Ｏ）_６］［（ＯＨ）（Ｃ_３Ｈ_２Ｎ_３Ｏ_３）］ＬｉｎＺｈｏｕ－Ｂｉｎ；ＣｈｅｎＣｈａｎｇ－Ｚｈａｎｇ；...
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Crystal Structure of Calcium Complex with Cyanuric Acid Ligand[Ca(C_3H_3N_3O_3-O)(H_2O)_6][(OH)(C_3H_2N_3O_3)] |
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| Lin Zhou-Bin,Chen Chang-Zhang,Gao Dong-Shou,Huang Xiao-Ying, Li Ding.Crystal Structure of Calcium Complex with Cyanuric Acid Ligand[Ca(C_3H_3N_3O_3-O)(H_2O)_6][(OH)(C_3H_2N_3O_3)][J].Chinese Journal of Structural Chemistry,1995(1). |
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| Authors: | Lin Zhou-Bin Chen Chang-Zhang Gao Dong-Shou Huang Xiao-Ying Li Ding |
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| Abstract: | The title compoundCa(C3H3N3O3)(H2O)6](OH)(C3H3N3O3)] crystallizes in the triclinic system,space group P1,with a=6.501(5),b=10.814(6),c=11.803(1) A,α=103.64(1),β=92. 72(3),γ=98. 82(4)°,V=793- 9(7) A3,Dc=l.77 g/cm3,Z=2,Mr=422. 32,λ(MoKα)=0.71069 A,μ=4.65 cm-1,F(000)=440,final R=0.045 and Rω=0.058 for 3422 observable reflections with I≥3σ(I).In the complex cation Ca (C3H3N3O3)(H2O)6]2+,the Ca2+ is coordinated by an oxygen atom from cyanuric acid ligand and six oxygen atoms from water molecules forming a distorted pentagonal bipyramid geometry.The complex anions, OH- and C3H2N3O3-,are bound with the complex cation(Ca(C3H3N3O3)(H2O)6]2+ by electrostatic force to form the title compound. |
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| Keywords: | synthesis crystal structure cyanuric acid calcium complex |
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