| CRYSTAL STRUCTURE OF (Et_4N)_4[Mo_2Fe_7S_8(SPh)_(12)] |
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| 摘 要： | <正> (Et4N)4Mo2Fe7S8(SPh)12] : Mw=2670.3, triclinic, p1, a=12.775(4), b=13.076(3), c=20.576(4)A, α=80.00(2), β=81.39(2), γ=61.51(2)°, V=2966.3(14) A3, Z=1, D=1.494 gcm-3, R=0.077 for 4031 observed reflections. The complex was prepared by reactions of (Et4N)2Fe4(SPh) 10] with (Et4N)2MoS4 in an ace-tonitrile solution. The structure of Mo2Fe7S8(SPh)12]4- anion is a double-cubane-like configuration bridged by a Fe(SPh)6 group.
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CRYSTAL STRUCTURE OF (Et_4N)_4[Mo_2Fe_7S_8(SPh)_( 12)] |
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| Abstract: | (Et4N)4Mo2Fe7S8(SPh)12] : Mw=2670.3, triclinic, p1, a=12.775(4), b=13.076(3), c=20.576(4)A, α=80.00(2), β=81.39(2), γ=61.51(2)°, V=2966.3(14) A3, Z=1, D=1.494 gcm-3, R=0.077 for 4031 observed reflections. The complex was prepared by reactions of (Et4N)2Fe4(SPh) 10] with (Et4N)2MoS4 in an ace-tonitrile solution. The structure of Mo2Fe7S8(SPh)12]4- anion is a double-cubane-like configuration bridged by a Fe(SPh)6 group. |
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