Substituted m-phenylene bridges as strong ferromagnetic couplers for Cu(II)-bridge-Cu(II) magnetic interactions: new perspectives |
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| Authors: | Paital Alok Ranjan Mitra Tamoghna Ray Debashis Wong Wing Tak Ribas-Ariño Jordi Novoa Juan J Ribas Joan Aromí Guillem |
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| Institution: | Department of Chemistry, Indian Institute of Technology, Kharagpur 721 302, India. |
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| Abstract: | Based on a combined theoretical-experimental study, we propose that substituted m-phenylene ligands (m-N-Phi-N) can act as tuneable strong ferromagnetic couplers connecting Cu(II) ions; a new complex presenting that bridge with J close to +15 cm(-1) has been suggested and synthesized. |
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