Controlled-potential coulometric studies on fluoride and sulphate complexes of neptunium (VI) |
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| Authors: | U M Kasar A R Joshi S K Patil |
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| Institution: | (1) Radiochemistry Division, Bhabha Atomic Research Centre, Trombay, 400085 Bombay, (India) |
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| Abstract: | Fluoride and sulphate complexing of Np(VI) has been studied by controlled-potential coulometry at a constant ionic strength. The values of 
1
*
and
2
*
for fluoride complexes were found to be 9.4 and 8.9, respectively, at an ionic strength  =0.5. At an ionic strength =1.0,
1
*
and
2
*
obtained were 6.6 and 10.5, respectively. Sulphate complexing of Np(VI) was studied only at an ionic strength =0.5. The value of
1
*
obtained was 5.6. |
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| Keywords: | |
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