Dimerization of Incomplete Cubane-Type Mo3S4(DTP)3 Units Linked by Bridging α, ω-Dicarboxylate |
| |
| Authors: | TANG Yan-Hong WU Ling QIN Ye-Yan KANG Yao LI Zhao-Ji YAO Yuan-Gen |
| |
| Institution: | State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Fuzhou 350002 |
| |
| Abstract: | Since the trinuclear molybdenum cluster compound Mo3S4(DTP)3(μ-DTP)(L) (DTP=diethyldithiophosphate, L=loosely-coordinated ligand) was reported1],a large number of monomeric trinuclear molybdenum derivatives have been synthesized from it by its diverse substitution reactions2]. This reaction provides a useful route to design cluster complexes with specific functions. By the reaction with α, ω-dicarboxylates, we successfully synthesized the first oligomer containing two incomplete cubane-typeMo3S4] cores formulated asMo3S4(DTP)3(DMF)]2η2-μ-OOC(CH2)3COO-μ-η2]) whose molecule structure is as follows: |
| |
| Keywords: | |
|
| 点击此处可从《高等学校化学学报》浏览原始摘要信息 |
| 点击此处可从《高等学校化学学报》下载免费的PDF全文 |
|
