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Synthesis of 5-alkylidene-2,5-dihydropyrrol-2-ones and their ring-transformation into 5,6-dihydrobenzo[h]chromones, 5,6,7,8-tetrahydrochromones and pyran-4-ones |
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| Authors: | Van TH Nguyen Joachim T Anders Qingjun Ma Regine Herbst-Irmer Peter Langer |
| Institution: | aInstitut für Chemie, Universität Rostock, Albert-Einstein-Strasse 3a, 18059 Rostock, Germany bInstitut für Anorganische Chemie, Universität Göttingen, Tammannstrasse 4, 37077 Göttingen, Germany cLeibniz-Institut für Katalyse e. V. an der Universität Rostock, Albert-Einstein-Strasse 29a, 18059 Rostock, Germany |
| Abstract: | Acid-mediated ring-transformations of 5-alkylidene-2,5-dihydropyrrol-2-ones, available by cyclization of 1,3-diketone dianions with bis(imidoyl) dichlorides of oxalic acid, resulted in formation of functionalized pyran-4-ones, such as 5,6-dihydrobenzoh]chromones and 5,6,7,8-tetrahydrochromones. |
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