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八苯基笼型倍半硅氧烷的官能化及其在高分子纳米复合材料中的应用
引用本文:王占彬,冷世伟,范金娟,王忠刚. 八苯基笼型倍半硅氧烷的官能化及其在高分子纳米复合材料中的应用[J]. 高分子通报, 2011, 0(9): 63-70
作者姓名:王占彬  冷世伟  范金娟  王忠刚
作者单位:大连理工大学化工学院高分子材料系,大连,116024
基金项目:国家自然基金(51073030,20874007); 教育部“新世纪优秀人才支持计划”项目(NCET-06-0280)资助
摘    要:笼型倍半硅氧烷(POSS)是具有独特分子结构的有机硅化合物,无机硅氧骨架核心为其提供良好的硬度和热稳定性,外围有机基团可增强与聚合物基体间的相容性,以它为前驱体可以制备分子级分散的有机/无机纳米高分子杂化材料。近年来,全芳香结构的八苯基笼型倍半硅氧烷因其高的耐热性和官能化方法的多样性尤其得到关注。本文重点综述了八苯基笼...

关 键 词:笼型倍半硅氧烷  八苯基笼形倍半硅氧烷  官能化  高分子纳米复合材料

Functionalized Octaphenylsilsesquioxanes and Their Applications in Polymer Nanocomposites
WANG Zhan-bin,,Leng Shi-wei,FAN Jin-juan,WANG Zhong-gang. Functionalized Octaphenylsilsesquioxanes and Their Applications in Polymer Nanocomposites[J]. Polymer Bulletin, 2011, 0(9): 63-70
Authors:WANG Zhan-bin    Leng Shi-wei  FAN Jin-juan  WANG Zhong-gang
Affiliation:WANG Zhan-bin1,2,Leng Shi-wei1,FAN Jin-juan2,WANG Zhong-gang1*(1.Department of Polymer Science and Materials,School of Chemical Engineering,Dalian University of Technology,Dalian 116024,2.Beijing Institute of Aeronautical Materials,Failure Analysis Center of AVIC,Beijing 100095,China)
Abstract:Polyhedral oligomeric silsesquioxane(POSS) is a category of organosilicon compounds with peculiar nanostructure,which has a well-defined cage-like inorganic silica-like core surrounded by various organic groups.The inorganic core provides it with high hardness,while the organic groups endow it with good compatibility with the polymer matrix.In recent years,octaphenylsilsesquioxane(OPS) received much attention owing to its excellent thermal stability and diverse functionalization methods because of the prese...
Keywords:Silsesquioxane  Octaphenylsilsesquioxane  Functionalization  Polymer nanocomposites  
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