Coexistence of superconductivity and magnetic order in YBa2Cu4O8

⁵⁷Fe Mössbauer spectroscopy, magnetic susceptibility and powder x-ray-diffraction measurements were used to study superconductivity and magnetic order in YBa₂(Cu_1?xFe_x)₄O_8+δ. T_c is decreasing with x, disappearing for x>x_c≈0.04. For xc iron substitutes Cu, predominantly in the Cu(1) site exhibiting a single quadrupole Mössbauer spectrum at 90 K. For x>x_c magnetic order is observed in the Cu(2) site, T_N=380 (5) K for x=0.1 and H_eff (Cu(2), 4.2 K)=510(2) kOe. However, the most surprising discovery is that for x=0.025, for which T_c=27(2) K, the Fe in the Cu(1) site orders magnetically at T_N=30(2) K and H_eff (Cu(1), 4.2 K)=461(2) kOe. The coexistence and competition between superconductivity and magnetic order in the Cu(1) and Cu(2) sites in YBa₂Cu₄O₈ are discussed in terms of the previously observed phase diagrams for Y_1?xPr_xBa₂(Cu_1?yFe_y)₃O_z.