Treatment of droplike clusters in nucleation theory using Reiss's method

The expression of the correction factor in nucleation theory is derived by extending the method Reiss used recently. is the factor appearing in the number of critical nuclei (formed as a vapor condenses into liquid drops) as a correction to the conventional theory. It is shown that=p _l / _g /kT, wherep _l is the pressure of the liquid phase inside the drop, _g , is the volume per molecule in the vapor phase,k is the Boltzmann constant, andT is the absolute temperature. The difference between this and Reiss's expression isp _l , which replaces hisp _g (the vapor pressure in equilibrium with the drop). The derived in this paper is compatible with the expression= _g / _l ( _l is the molecular volume in the liquid phase) previously proposed by the present author.