| 氮功能化大环化合物及其Ni(Ⅱ)配合物的合成和谱学研究 |
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| 引用本文： | 王世范,谢复新,倪诗圣. 氮功能化大环化合物及其Ni(Ⅱ)配合物的合成和谱学研究[J]. 光谱学与光谱分析, 2000, 20(1): 44-48 |
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| 作者姓名： | 王世范 谢复新 倪诗圣 |
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| 作者单位： | 华东冶金学院化工系,243002,马鞍山;安徽大学化学系,230039,合肥 |
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| 摘 要： | 以丙酮,乙二胺,溴乙酸乙酯为原料合成了三种新的氮功能化四氮杂大环化合物的配合物,用元素分析,电子光谱,红外光谱,氢核磁共振谱和质谱对它们进行了研究。
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| 关 键 词： | 大环 大环配体 配合物 合成 表征 |
| 修稿时间： | 1998-06-06 |
Synthesis and Spectroscopic Studies of New N-functionalized Macrocyclic Compounds and Complex |
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| Shifan WANG,Fuxin XIE,Shisheng NI. Synthesis and Spectroscopic Studies of New N-functionalized Macrocyclic Compounds and Complex[J]. Spectroscopy and Spectral Analysis, 2000, 20(1): 44-48 |
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| Authors: | Shifan WANG Fuxin XIE Shisheng NI |
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| Affiliation: | Chemical Engineering Department, East China Institute of Metallurgy, 243002 Maanshan. |
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| Abstract: | Three new N-functionalized tetraazamacrocyclic compounds, C-messo-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane- N,N',N,N'-tetrakis (ethyl acetate) (A), C-messo-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetra- azacyclotetradecane-N,N,'N,N'-tetraacetic acid (H4L) and the hydrobromide of H4L have been synthesized and the complex Na2[NiL].2C2H5OH has been prepared as well. The macroyclic compounds and the complex have been studied by electronic spectrum, infrared spectrum, 1H NMR, MS and elemental analysis. |
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| Keywords: | Macrocycle Macrocyclic compound Complex Synthesis Characterization |
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