Synthesis of Optically Pure 3<Emphasis Type="Italic">R</Emphasis>-methylcyclopentan-1-one from L-(-)-menthol |
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| Authors: | G Yu Ishmuratov M P Yakovleva V A Ganieva G R Gareeva R R Muslukhov G A Tolstikov |
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| Institution: | (1) Institute of Organic Chemistry, Ufa Scientific Center, Russian Academy of Sciences, 450054 Ufa, pr. Oktyabrya, 71, Russia;(2) Birsk State Social-Pedagogical Academy, 452320 Birsk, ul. Internatsional'naya, 10, Russia |
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| Abstract: | Synthesis of optically pure 3R-methylcyclopentan-1-one using in the key step Dieckmann cyclization of diisopropyl 3R-methylhexan-1,6-dioate,
which is accessible from L-(-)-menthol, was proposed.
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Translated from Khimiya Prirodnykh Soedinenii, No. 5, pp. 448–450, September–October, 2005. |
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| Keywords: | L-(-)-menthol diisopropyl 3R-methylhexan-1 6-dioate isopropyl 4R-methyl-2-oxocyclopentan-1-carboxylate 3R-methylcyclopentan-1-one Dieckmann cyclization |
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