Reaction of 2,6-dibenzylidenecyclohexanone with phosphorus pentachloride: Triple functionalization of the isosemiquinoid system |
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| Authors: | V. A. Nikanorov A. D. Rogachev M. V. Galakhov T. M. Shcherbina D. V. Zagorevskii V. I. Rozenberg O. A. Reutov V. V. Kaverin V. P. Yur'ev |
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| Affiliation: | (1) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813 Moscow, Russian Federation;(2) Joint-Stock Company !["ldquo"]("/content/t35683760372166x/xlarge8220.gif") Scientific Research and Planning Institute of Monomers, 106A prosp. Lenina, 300026 Tula, Russian Federation |
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| Abstract: | The reaction of 2,6-dibenzylidenecyclohexanone with PCl5 occursvia the sequential stages of desoxychlorination and substitutional phosphorylation to form (after oxidation, methoxylation, and hydrolysis on the surface of the chromatographic SiO2 adsorbent) organophosphorus products of the 1-(a-chloro-, a-hydroxy-, or  -alkoxy)benzyl-2-chloro-3-(-(dimethylphosphoryl)benzylidene)cyclobex-1-ene series.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 441–443, February, 1996. |
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| Keywords: | dienones phosphorylation desoxychlorination methoxylation hydrolysis phosphorus(v) derivatives solid-phase functionalization on the surface of chromatographic adsorbents |
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