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UV-vis辐照下H2Fe2Ti3O10/TiO2插层材料光催化活性的研究
引用本文:黄昀昉,吴季怀,李涛海,林建明,黄妙良,魏月琳.UV-vis辐照下H2Fe2Ti3O10/TiO2插层材料光催化活性的研究[J].人工晶体学报,2007,36(5):978-984.
作者姓名:黄昀昉  吴季怀  李涛海  林建明  黄妙良  魏月琳
作者单位:华侨大学材料物理化学研究所,泉州,362021
摘    要:在高压汞灯辐照下,通过插入反应将H2Fe2Ti3O10与n-C3H7NH2/C2H5OH和TiO2溶胶制备出H2Fe2Ti3O10/TiO2插层复合物.插入TiO2的层状钙钛矿化合物H2Fe2Ti3O10在UV-vis辐照下表现出高活性.实验结果表明H2Fe2Ti3O10/TiO2作为光催化剂在可见光(λ>420nm)下辐照24h,降解甲基橙的速率为59.0;.与相同条件下降解率只有24;的商用光催化剂TiO2(Degussa P-25)相比,H2Fe2Ti3O10/TiO2表现出了更高的光催化活性.

关 键 词:光催化活性  插层材料  H2Fe2Ti3O10  TiO2  
文章编号:1000-985X(2007)05-978-07
修稿时间:2007-02-10

Photocatalytic Activities of Layered Intercalated Materials H2Fe2Ti3O10/TiO2 under UV and Visible Light Irradiation
HUANG Yun-fang,WU Ji-huai,LI Tao-hai,LIN Jian-ming,HUANG Miao-liang,WEI Yue-lin.Photocatalytic Activities of Layered Intercalated Materials H2Fe2Ti3O10/TiO2 under UV and Visible Light Irradiation[J].Journal of Synthetic Crystals,2007,36(5):978-984.
Authors:HUANG Yun-fang  WU Ji-huai  LI Tao-hai  LIN Jian-ming  HUANG Miao-liang  WEI Yue-lin
Institution:Institute of Materials Physical Chemistry, Huaqiao University, Quanzhou 362021, China
Abstract:A new nanocomposite,H2Fe2Ti3O10/TiO2 was synthesized by the stepwise intercalation reactions of H2Fe2Ti3O10 with n-C3H7NH2/C2H5OH mixed solution and acid TiO2 colloid solution. H2Fe2Ti3O10,a layered perovskite type compound with TiO2-loading, exhibited a high activity for decomposition of methyl orange under UV and visible light irradiation.The experimental results showed that methyl orange was degraded with the decomposition ratio of 59.0% by using H2Fe2Ti3O10/TiO2 as photocatalyst under visible light(λ>420nm)irradiation for 24h. The H2Fe2Ti3O10/TiO2 possessed higher photocatalytic activity than those commercial titania powder(Degussa P-25) which showed the decomposition ratio just only 24% under same condition.
Keywords:H2Fe2Ti3O10  TiO2  photocatalytic activity  intercalated material  H2Fe2Ti3O10  TiO2
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