Short synthesis of (-)-cephalotaxine using a radical cascade |
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Authors: | Taniguchi Tsuyoshi Ishibashi Hiroyuki |
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Institution: | Division of Pharmaceutical Sciences, Graduate School of Natural Science and Technology, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, Japan. |
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Abstract: | The short total synthesis of (-)-cephalotaxine is described. The concise construction of the pentacyclic core of this alkaloid was achieved by a radical cascade involving 7-endo and 5-endo cyclizations. |
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