New pyrrolopyridazine derivatives as blue organic luminophors |
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Authors: | KMK Swamy Su Jung Han Ju Hee Kim Hyunjin Bang Sung-Jin Kim Juyoung Yoon |
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Institution: | a Division of Nano Sciences, Ewha Womans University, 11-1 Daehyon-Dong, Sodaemun-Ku, Seoul 120-750, Korea b Department of Chemistry, Ewha Womans University, 11-1 Daehyon-Dong, Sodaemun-Ku, Seoul 120-750, Korea |
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Abstract: | New pyrrolopyridazine derivatives were synthesized as potential blue organic luminophors. Three different classes of pyrrolopyridazine derivatives were made, for example, aryl groups directly connected to the core PPY (pyrrolo1,2-b]pyridazine-5,6,7-tricarboxylic acid trimethyl ester) moiety, aryl groups connected to the PPY via a vinylene linker and aryl groups connected to the PPY via an acetylene linker. Their optical and electrochemical properties were productively compared. One of the derivatives 2 showed a relative quantum yield as high as 0.9. Compound 8 in the vinyl bridged pyrrolopyridazine series has been characterized by its X-ray crystal structure analysis. |
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Keywords: | Pyrrolopyridazine Fluorescence Luminophor Blue luminophor Sonogashira coupling Blue shift Red shift |
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