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Pd2(dba)3/Xantphos-catalyzed cross-coupling of thiols and aryl bromides/triflates |
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| Authors: | Clotilde Mispelaere-Canivet Stéphane Perrio Pierre Beslin |
| Institution: | a Laboratoire de Chimie Moléculaire et Thio-organique (UMR CNRS 6507), ENSICaen-Université de Caen Basse-Normandie, 6 Boulevard du Maréchal Juin, F-14050 Caen, France b RHODIA, Centre de Recherches de Lyon, POP/ISV, 85 Avenue des Frères Perret, BP 62, F-69192 Saint-Fons, France |
| Abstract: | The cross-coupling of aliphatic and aromatic thiols and aryl bromides/triflates mediated by a Pd2(dba)3/Xantphos catalytic system in refluxing xylene (140 °C) affords the corresponding aryl thioethers in good to excellent yields. |
| Keywords: | Palladium catalysis Thiol cross-coupling |
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