Applications of surfactant-modified clays to synthetic organic chemistry |
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Authors: | M Ghiaci ME Sedaghat RJ Kalbasi A Abbaspur |
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Institution: | Department of Chemistry, Isfahan University of Technology, Isfahan 84156, Iran |
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Abstract: | Two triphase catalysts (SLL) have been developed for organic phase-aqueous phase reactions catalyzed by suitable modified clay (solid phase). These triphase catalysts have been applied to nucleophilic displacement on activated (benzylic) as well as unactivated organic halides and provide a convenient and effective method of preparation of the corresponding products. Other useful transformations to, which these triphase catalysts have been successfully applied are the synthesis of 9,9-dichloro bicyclo6.1.0]nonane, O-alkylation and C-alkylation of β-naphthol. |
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Keywords: | Triphase catalysis Nucleophilic substitution Surfactant modified clay Phase-transfer |
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