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Lewis acid promoted reactions of γ,γ-dialkoxyallylic zirconium species with various carbonyl compounds
Authors:Hisanaka Ito  Takeo Taguchi
Institution:a Tokyo University of Pharmacy and Life Science, 1432-1 Horinouchi, Hachioji, Tokyo 192-0392, Japan
b Tokyo Women's Medical University, 8-1 Kawada-cho, Shinjuku-ku, Tokyo 162-8666, Japan
Abstract:The reactions of γ,γ-dialkoxyallylic zirconium species with carbonyl compounds in the presence of Lewis acid are reported. The reactivity of γ,γ-dialkoxyallylic zirconium species and reaction pathway were strongly dependent on the structure and electrostatic nature of the carbonyl compounds.
Keywords:Lewis acid  Zirconium species  Cyclopropane derivatives
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