Michael additions catalyzed by phosphines. An overlooked synthetic method |
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| Authors: | Carolina Gimbert,Marcial Moreno-Mañ as |
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| Affiliation: | Department of Chemistry, Universitat Autònoma de Barcelona, 08193 Cerdanyola, Barcelona, Spain |
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| Abstract: | ![]()
Triphenylphosphine and tributylphosphine are excellent catalysts for Michael additions. Many β-dicarbonyl compounds and electron-poor olefins, including sterically demanding partners, react successfully. The Michael addition catalyzed by phosphines deserves attention in its own right as a useful synthetic method. |
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| Keywords: | Organocatalysis Phosphines Conjugate addition β-Dicarbonyl compounds |
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