| Syntheses and Crystal Structures of Two Coordination Polymers of Cobalt and Cadmium Assembled by 4,4ˊ-(Ethane-1,2-diyldioxy)dibenzoic Acid |
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| 引用本文： | 王庆伟,王亚男,齐晓飞,李秀梅,刘博.Syntheses and Crystal Structures of Two Coordination Polymers of Cobalt and Cadmium Assembled by 4,4ˊ-(Ethane-1,2-diyldioxy)dibenzoic Acid[J].结构化学,2014,33(11):1629-1635. |
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| 作者姓名： | 王庆伟 王亚男 齐晓飞 李秀梅 刘博 |
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| 作者单位： | [1]Key Laboratory of Preparation and Applications of Environmental Friendly Materials (Jilin Normal University), Ministry of Education, Siping, Jilin 136000, China; [2]Faculty of Chemistry, Tonghua Normal University, Tonghua, Jilin 134002, China |
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| 基金项目： | supported by the Science and Technology Development Project of Jilin Provincial Science&Technology Department(201205080) |
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| 摘 要： | Two new metal-organic coordination polymers Co0.5（Heoba）（bib）0.5]2n（1） and Cd（eoba）（phen）]n（2）（H2eoba = 4,4-（ethane-1,2-diyldioxy）dibenzoic acid, bib = 1,4-bis（imidazol-1-yl）-butane, phen = 1,10-phenanthroline） have been hydrothermally synthesized and structurally characterized by elemental analysis, IR spectrum, TG and single-crystal X-ray diffraction. Complex 1 is a 2D network structure, and complex 2 exhibits a 3D network structure. Moreover, the luminescent property of complex 2 has been investigated in the solid state.
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| 关 键 词： | 配位聚合物 水热合成 苯甲酸 晶体结构 乙烷 单晶X射线衍射 组装 二维网状结构 |
Syntheses and Crystal Structures of Two Coordination Polymers of Cobalt and Cadmium Assembled by 4,4'-(Ethane-1,2-diyldioxy)dibenzoic Acid |
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| WANG Qing-Wei
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WANG Ya-Nan
,
QI Xiao-Fei
,
LI Xiu-Mei
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LIU Bo.Syntheses and Crystal Structures of Two Coordination Polymers of Cobalt and Cadmium Assembled by 4,4'-(Ethane-1,2-diyldioxy)dibenzoic Acid[J].Chinese Journal of Structural Chemistry,2014,33(11):1629-1635. |
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| Authors: | WANG Qing-Wei WANG Ya-Nan QI Xiao-Fei LI Xiu-Mei LIU Bo |
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| Institution: | 1. Key Laboratory of Preparation and Applications of Environmental Friendly Materials(Jilin Normal University), Ministry of Education, Siping, Jilin 136000, China
2. Faculty of Chemistry, Tonghua Normal University, Tonghua, Jilin 134002, China |
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| Abstract: | Two new metal-organic coordination polymers Co0.5(Heoba)(bib)0.5]2n(1) and Cd(eoba)(phen)]n(2)(H2eoba = 4,4-(ethane-1,2-diyldioxy)dibenzoic acid, bib = 1,4-bis(imidazol-1-yl)-butane, phen = 1,10-phenanthroline) have been hydrothermally synthesized and structurally characterized by elemental analysis, IR spectrum, TG and single-crystal X-ray diffraction. Complex 1 is a 2D network structure, and complex 2 exhibits a 3D network structure. Moreover, the luminescent property of complex 2 has been investigated in the solid state. |
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| Keywords: | hydrothermal synthesis crystal structure cobalt complex cadmium complex |
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