Iodochlorination of silyl- and germylphenylacetylenes |
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| Authors: | Anastasia A. Selina Anna E. Zhachkina Sergey S. Karlov Andrei V. Churakov Galina S. Zaitseva |
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| Affiliation: | 1. Chemistry Department, Moscow State University, Moscow, Russia;2. Institute of General and Inorganic Chemistry, Russian Academy of Science, Moscow, Russia |
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| Abstract: | ![]()
Reactions of Si- and Ge-substituted alkynes with KICl2 were investigated. (1-Germatranyl)-phenylacetylenes and (triphenylsilyl)phenylacetylene gave Z-iodochloroalkenes with chlorine and phenyl groups attached to the same carbon atom. Adduct structures were confirmed by X-ray diffraction studies. © 2004 Wiley Periodicals, Inc. Heteroatom Chem 15:169–174, 2004; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20001 |
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