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Exciting lattice oxygen of nickel–iron bi-metal alkoxide for efficient electrochemical oxygen evolution reaction
作者姓名:Saihang Zhang  Senchuan Huang  Fengzhan Sun  Yinghui Li  Li Ren  Hao Xu  Zhao Li  Yifei Liu  Wei Li  Lina Chong  Jianxin Zou
作者单位:1. National Engineering Research Center of Light Alloy Net Forming & State Key Laboratory of Metal Matrix Composites, Center of Hydrogen Science, School of Materials Science and Engineering, Shanghai Jiao Tong University;2. Department of Chemistry, Laboratory of Advanced Materials, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, iChEM and State Key Laboratory of Molecular Engineering of Polymers, College of Chemistry and Materials, Fudan University
基金项目:the staff at Beamline (BL08U1-A and BL11B) of the Shanghai Synchrotron Radiation Facility (SSRF);;the support from the National Key Research & Development Program of China (2022YFB3803700);;the support through the Overseas Outstanding Youth Fund and Shanghai Pujiang Talent Project (21PJ1408500);
摘    要:High efficiency, cost-effective and durable electrocatalysts are of pivotal importance in energy conversion and storage systems. The electro-oxidation of water to oxygen plays a crucial role in such energy conversion technologies. Herein, we report a robust method for the synthesis of a bimetallic alkoxide for efficient oxygen evolution reaction(OER) for alkaline electrolysis, which yields current density of 10 mA cm-2 at an overpotential of 215 mV in 0.1 M KOH electrolyte. The cataly...

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