Konsekutive umlagerungen eines 2-azabicyclo[2.2.2]octen-derivates in das 1-azatricyclo[3.2.1.O2,7]- und das 6-azabicyclo[3.2.1]octan-system |
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| Affiliation: | 1. College of Nursing, Texas Woman’s University, Dallas, TX, United States;2. College of Nursing, The University of Texas at Tyler, Tyler, TX, United States;1. UES Inc., Air Force Research Laboratory, 711th Human Performance Wing/RHXBC, 2510 Fifth Street, Area B, Building 840, Wright-Patterson AFB, OH 45433, USA;2. The Henry M. Jackson Foundation for the Advancement of Military Medicine, Air Force Research Laboratory, 711th Human Performance Wing/RHXB, Wright-Patterson AFB, OH 45433, USA;3. Oak Ridge Institute of Science & Education, Air Force Research Laboratory, 711th Human Performance Wing/RHCP, Wright-Patterson AFB, OH 45433, USA;4. InfoSciTex Corp., Air Force Research Laboratory, 711th Human Performance Wing/RHCP, Wright-Patterson AFB, OH 45433, USA;5. Abbott Nutrition, Columbus, OH 43219, USA;6. Beckman Institute, University of Illinois, Urbana, IL 61801, USA;7. Air Force Research Laboratory, 711th Human Performance Wing/RH, Wright-Patterson AFB, OH 45433, USA;1. Centre for Gerontology and Rehabilitation, School of Medicine, University College Cork, Cork, Ireland;2. Pharmaceutical Care Research Group, School of Pharmacy, University College Cork, Cork, Ireland;3. School of Public Health, University College Cork, Cork, Ireland;4. Health Behaviour Change Research Group, School of Psychology, National University of Ireland, Galway, Ireland;5. School of Nursing, Psychotherapy and Community Health, Dublin City University, Dublin, Ireland;6. Centre for Health Policy and Management, Trinity College Dublin, Dublin, Ireland |
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| Abstract: | ![]()
In contrast to similar ring system the O-tosyl derivative 2 is rearranged exclusively to the tricyclic aziridine 4. Further tosylation produces the bicyclic tosyl amide 5. The corresponding O-benzoyl-derivatives 6 rearrange in the usual manner with π-assistence to give 7. |
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