A synthesis of a doubly-bridged [24] annulene |
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| Affiliation: | 1. Division of Food and Chemical Biology, Faculty of Fisheries, Kagoshima University, 890-0056 Kagoshima, Japan;2. Department of Domestic Science, Kagoshima Women''s College, Kagoshima 890-8565, Japan;3. College of Pharmaceutical Sciences, School of Clinical Pharmacy, Matsuyama University, 790-8578, Ehime, Japan;4. Department of Molecular Oncology, Graduate School of Medical and Dental Sciences, Kagoshima University, 890-8544 Kagoshima, Japan;5. Center for the Research of Advanced Diagnosis and Therapy of Cancer, Graduate School of Medical and Dental Sciences, Kagoshima University, 8-35-1 Sakuragaoka, Kagoshima 890-8544, Japan |
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| Abstract: | ![]()
Reductive coupling of 1, 6-bis(2-formylvinyl)cyclohepta-1, 3, 5-triene with a low-valent titanium reagent afforded a paratropic bismethano [24] annulene. |
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