Le formamide,un substitut de l'eau XI: Effet du formamide sur les reactions d'echange chlore-fluor dans les conditions de transfert de phase liquide-solide |
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| Affiliation: | 1. Instituto de Investigaciones Biomédicas “Alberto Sols”, CSIC-UAM Madrid, Spain;2. Centro de Investigación Biomédica en Red de Enfermedades Cardiovasculares (CIBER-CV), Instituto de Salud Carlos III, Madrid, Spain;3. Instituto de Investigación del Hospital La Paz, IdiPaz, Madrid, Spain;4. Departamento de Farmacología, Farmacognosia y Botánica, Facultad de Farmacia, Universidad Complutense de Madrid, Madrid, Spain;1. NFMLab - D.C.M.I.C. “Giulio Natta”, Politecnico di Milano, Via L. Mancinelli 7, 20131 Milan, Italy;2. Thermo Fisher Scientific, Strada Rivoltana, 20090, Rodano, Milan, Italy;3. San Filippo Neri Hospital, Department of Anesthesia and Intensive Care, Rome, Italy;1. KTH Royal Institute of Technology, Dept. Chemistry, Div. Surface and Corrosion Science, Drottning Kristinas väg 51, SE-100 44 Stockholm, Sweden;2. SP Technical Research Institute of Sweden, Chemistry, Materials and Surfaces, P.O. Box 5607, SE-114 86 Stockholm, Sweden;1. School of Medicine, Diabetes Complication Research Centre, UCD Conway Institute, University College Dublin, Belfield, Dublin 4, Ireland;2. Centre for Synthesis and Chemical Biology, School of Chemistry, UCD Conway Institute, University College Dublin, Belfield, Dublin 4, Ireland;3. William Harvey Research Institute, Queen Mary University London, London, UK;4. Trinity Biomedical Sciences Institute, Trinity College Dublin, Dublin 2, Ireland;5. School of Biotechnology, Dublin City University, Glasnevin, Dublin 9, Ireland;6. Actelion Pharmaceuticals Ltd, Gewerbestrasse 16, 4123, Allschwil, Switzerland |
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| Abstract: | ![]()
The fluoride-chloride exchange reaction RCl + KF → RF + KCl catalysed by ammonium salts takes place in presence of formamide in place of water, faster and qith better yields. |
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