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Energy dependence of the fragmentation of some isomeric [C6H12]+˙ ions |
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| Authors: | Jan A Herman Yip-Hoi Li Alex G Harrison |
| Institution: | 1. Department of Chemistry, University of Toronto, Toronto, Canada M5S 1A1
Visiting Professor 1979–1980. Département de Chimie, Université Laval, Québec, Québec, Canada.;2. Department of Chemistry, University of Toronto, Toronto, Canada M5S 1A1 |
| Abstract: | The charge exchange mass spectra of 14 C6H12 isomers have been determined using CS2]+˙, COS]+˙, Xe]+˙, CO]+˙, N2]+˙ and Ar]+˙ as the major reactant ions covering the recombination energy range from ∼10.2 eV to ∼15.8 eV. From the charge exchange data breakdown graphs have been constructed expressing the energy dependence of the fragmentation of the isomeric C6H12]+˙ molecular ions. The electron impact mass spectra are discussed in relation to these breakdown graphs and approximate internal energy distribution functions derived from photoelectron spectra. |
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