Studies in spiroheterocycles. Part V. Synthesis of new fluorinated spiro[3H-indole-3,2′-oxiran]-2(1H)-ones |
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Authors: | Krishna C. Joshi Renuka Jain Saroj Garg |
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Affiliation: | Department of Chemistry, University of Rajasthan, Jaipur-302004, India |
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Abstract: | Reinvestigation of the reaction of 3-aroylmethyleneindol-2-ones with hydrogen peroxide has revealed that a 1:1 isomeric mixture of spiro[3H-indole-3,2′-oxiran]-2(1H)-ones is formed. The structures of the two isomers have been confirmed by their ir, pmr and mass spectral studies. Mass fragmentation patterns of these compounds are discussed. |
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