A simple and stereoselective synthesis of 7-azabicyclo[2.2.1]-heptane-1,2,3,4-tetracarboxylates |
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Authors: | Tadataka Zaima Chikashi Matsuno Yoshiharu Matsunaga Keiryo Mitsuhashi |
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Institution: | 1. Department of Chemistry, College of Technology, Kanagawa University, Yokohama 221, Japan Keiryo Mitsuhashi;2. Department of Chemistry, College of Technology, Seikei University, Musashino-shi, Tokyo 180, Japan |
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Abstract: | The photoinitiated reaction of 1,1′-bis(methoxycarbonyl)divinylamine with various maleates and fumarates afforded novel 7-azabicyclo2.2.1]heptane-1,2,3,4-tetracarboxylates. The spectral investigation of the products showed that the reaction proceeded stereoselectively, retaining the original configuration of the reagents. |
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