Synthesis, characterization and thermal degradation of functional benzoxazine monomers and polymers containing phenylphosphine oxide |
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Authors: | Seong-Woo Choi |
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Institution: | Department of Macromolecular Science and Engineering, Case Western Reserve University, Cleveland, OH 44106-7202, 10900 Euclid Avenue, United States |
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Abstract: | Three phosphorus-containing bisphenol compounds, bis(4-hydroxyphenyl)phenylphosphine oxide (BHPPO), bis(4-hydroxyphenoxyphenyl)phenylphosphine oxide (BPPPO), and bis(4-hydroxyphenoxy)phenylphosphine oxide (BPHPPO) have been synthesized as starting materials for the synthesis of benzoxazine monomers. Benzoxazine monomers containing phenylphosphine oxide have been prepared and subsequently characterized by FT-IR and 1H NMR. The monomers are thermally initiated and polymerized via ring-opening polymerization. Thermogravimetric analysis indicates that phosphorylation can have a profound effect on increasing char yield and on thermal degradation temperatures. |
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Keywords: | Benzoxazine Phosphorous Phenylphosphine oxide Thermogravimetric analysis |
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