Decomposition of sodium hypochlorite in an aqueous solution in the presence of 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) nitroxyl radical as a catalyst |
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| Authors: | I Yu Ponedel’kina E A Khaibrakhmanova D Sh Sabirov V N Odinokov |
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| Institution: | 1160. Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, 141 prosp. Oktyabrya, 450075, Ufa, Bashkortostan, Russian Federation
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| Abstract: | Nitroxyl radical TEMPO is found to catalyze the decomposition of sodium hypochlorite in an aqueous-alkali medium. The mechanism of NaOCl decomposition to form ClO· radical is proposed which involves protonated TEMPO, oxoammonium salt TEMPO+, and hydroxyl radical. |
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