Synthesis of glycosylcurcuminoids |
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| Authors: | Mohri Kunihiko Watanabe Yuhya Yoshida Yuki Satoh Mitsuru Isobe Kimiaki Sugimoto Naoki Tsuda Yoshisuke |
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| Institution: | Showa Pharmaceutical University, Tokyo, Japan. mohri@ac.shoyaku.ac.jp |
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| Abstract: | Condensation of glycosylated arylaldehyde with acetylacetone-B(2)O(3) complex gave a corresponding diglycosylcurcuminoid, and a similar reaction using a mixture of arylaldehyde and glycosylarylaldehyde gave an unsymmetrical monoglycosylcurcuminoid, both as boron-complexes. The boron was removed from the complexes by heating in methanol, thus achieving the synthesis of di- and mono-glycosylcurcuminoids. |
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