| Syntheses,Crystal Structures and Luminescent and Magnetic Properties of Cerium(Ⅲ) and Zinc(Ⅱ) Coordination Compounds Constructed from 3,5-Dibromobenzoic Acid |
| |
| 引用本文： | 高竹青,李红晋,顾金忠.Syntheses,Crystal Structures and Luminescent and Magnetic Properties of Cerium(Ⅲ) and Zinc(Ⅱ) Coordination Compounds Constructed from 3,5-Dibromobenzoic Acid[J].结构化学,2015(2):227-234. |
| |
| 作者姓名： | 高竹青 李红晋 顾金忠 |
| |
| 作者单位： | School of Chemical and Biological Engineering,Taiyuan University of Science and Technology;College of Chemistry and Chemical Engineering, Lanzhou University |
| |
| 基金项目： | supported by the Natural Science Foundation of Shanxi Province(No.2013011011-6);the Subject Team of Taiyuan University of Science and Technology |
| |
| 摘 要： | Two coordination compounds, namely Ce(3,5-Br2BC)3(3,5-HBr2BC)]n(1) and Zn(3,5-Br2BC)2(phen)](2, 3,5-HBr2 BC = 3,5-dibromobenzoic acid, phen = 1,10-phenanthroline), were assembled. Single-crystal X-ray diffraction studies show that compound 1 possesses a 1D chain coordination network, which is further extended into a 3D supramolecular architecture via Br···Br and Br···O halogen bonding. Compound 2 consists of a mononuclear molecule, which is assembled to a 3D supramolecular framework through C–H···O hydrogen bond, π-π stacking interactions and Br···π halogen bonding. Luminescent and magnetic properties of both compounds have also been studied.
|
| 关 键 词： | coordination compound 3 5-dibromobenzoic acid luminescent properties magnetic properties |
| 本文献已被 CNKI 等数据库收录！ |
|
