The enthalpy of formation of fullerene fluoride C<Subscript>60</Subscript>F<Subscript>18</Subscript> and the C-F bond energy期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

The enthalpy of formation of fullerene fluoride C60F18 and the C-F bond energy

Authors:	T. S. Papina V. A. Luk’yanova A. A. Goryunkov I. N. Ioffe I. V. Gol’dt A. G. Buyanovskaya N. M. Kabaeva L. N. Sidorov

Affiliation:	(1) Faculty of Chemistry, Moscow State University, Leninskie gory, Moscow, 119992, Russia;(2) Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, Moscow, GSP-1, 117813, Russia

Abstract:	The enthalpy of combustion of crystalline fullerene fluoride C₆₀F₁₈ was determined in an isoperibolic calorimeter with a rotating platinized bomb, and the enthalpy of formation of the compound was calculated. The enthalpy of sublimation of C₆₀F₁₈ measured earlier was used to calculate the enthalpy of formation of fullerene fluoride in the gas phase and the mean enthalpy of dissociation of C-F bonds in this compound.

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