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Synthesis and Crystal Structure of DinuclearCadmium Complex [Cd2(phen)4(fca)2](ClO4)2-(H2O)2
作者姓名:YANG Jia-Xianga ZHANG Zeb WU Jie-Yinga TIAN Yu-Penga  c② DU Pengb LIU Qing-Liangb FUN Hoong Kund C. Suchadad a (Department of Chemistry  Anhui University  Hefei 230039  China) b (Department of Chemistry  University of Science and Technology of China  Hefei 230026  China) c (State Key Laboratory of Coordination Chemistry  Nanjing University  Nanjing 210093  China) d (X-ray Crystallography Unit  School of Physics  University Sains Malaysia 11800 USM  Penang  Malaysia)
作者单位:YANG Jia-Xianga ZHANG Zeb WU Jie-Yinga TIAN Yu-Penga,c② DU Pengb LIU Qing-Liangb FUN Hoong Kund C. Suchadad a (Department of Chemistry,Anhui University,Hefei 230039,China) b (Department of Chemistry,University of Science and Technology of China,Hefei 230026,China) c (State Key Laboratory of Coordination Chemistry,Nanjing University,Nanjing 210093,China) d (X-ray Crystallography Unit,School of Physics,University Sains Malaysia 11800 USM,Penang,Malaysia)
基金项目:the grants from the State Key Program of China,the National Natural Science Foundation of China (29871001,20071001) and the Committee of Education of Anhui province
摘    要:1 INTRODUCTION During the search of molecule-based materials with interesting properties such as catalysis, cla- thration etc., much attention has been focused on the synthesis of one-, two- and three-dimensional extended solids involving cadmium[1], as its d10 configuration permits a wide variety of geometries and coordination numbers. Rigid bridged ligands such as carboxylate groups are frequently used to construct these materials. Therefore, the coordi- nation chemistry of Cd(Ⅱ) ca…

关 键 词:合成  晶体结构  双核镉配合物  [Cd2(phen)4(fca)2](ClO4)2-(H2O)2  二茂铁衍生物
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