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水热法制备高度取向的氧化锌纳米棒阵列
引用本文:郭敏,刁鹏,蔡生民.水热法制备高度取向的氧化锌纳米棒阵列[J].高等学校化学学报,2004,25(2):345-347.
作者姓名:郭敏  刁鹏  蔡生民
作者单位:1. 北京大学化学与分子工程学院, 北京 100871; 2. 北京航空航天大学材料科学与工程学院, 北京 100083
基金项目:国家自然科学基金 (批准号 :2 0 0 73 0 0 3 )资助
摘    要:氧化锌的激子结合能(60meV)及光增益系数(300cm^-1)比GaN的(25meV,100cm^-1)还高,这一特点使它成为紫外半导体激光发射材料的研究热点。最近,Yang等成功地观测到规则的ZnO纳米线阵列的激光发射现象,更加激起了人们合成一维高度有序ZnO纳米结构的热情,由于一维ZnO

关 键 词:ZnO  纳米棒阵列膜  水热法  
文章编号:0251-0790(2004)02-0345-03
收稿时间:2003-08-26

Hydrothermal Preparation of Highly-oriented ZnO Nanorod Array Films
GUO Min ,DIAO Peng ,CAI Sheng-Min.Hydrothermal Preparation of Highly-oriented ZnO Nanorod Array Films[J].Chemical Research In Chinese Universities,2004,25(2):345-347.
Authors:GUO Min  DIAO Peng  CAI Sheng-Min
Institution:1. College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China; 2. School of Materials Science and Engineering, Beijing University of Aeronautics and Astronautics, Beijing 100083, China
Abstract:By using a simply and low-temperature hydrothermal method, ZnO nanorod array films with narrow size distribution and high orientation consistence were successfully prepared on ITO substrates, which were pre-treated with ZnO colloid solution. The obtained ZnO nanostructure was characterized by XRD and SEM. The results of characterization indicate that the nanorods are high-quality single crystals growing along (001) direction with a high consistent orientation perpendicular to the substrate. SEM images show that the nanorods have a very narrow size distribution of 20—50 nm with the average diameter about 40 nm. The room temperature photoluminescence of the as-prepared ZnO films exhibits a strong UV emission at about 390 nm and a weak emission at about 460 nm. The ease of fabricating high-quality ZnO nanorod arrays in large scales will greatly promote the fundamental research and practical applications of the ordered one-dimention ZnO structure in various fields of nanoscale science and technology.
Keywords:ZnO  Nanorod array films  Hydrothermal method
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